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Angelina Jolie spent much of 2006 making headlines in her real life roles as mother, lover and humanitarian, but now she’s back on the big screen, disappearing into another compelling character—the long-suffering wife of a Central Intelligence Agency operative (Matt Damon) who neglects him family as he becomes consumed by Cold War paranoia in The Good Shepherd, director Robert De Niro’s Godfather-style saga of the CIA’s history. Jolie herself is far less secretive than the CIA, and she gave Hollywood.com a peek into her world.