Brad Pitt

One of the hottest men in Hollywood, this Oklahoma-born blond appeared in a handful of TV-movies and guest spots before becoming an overnight sensation with his sexy supporting turn as a robber in Thelma & Louise in 1991. Pitt graduated to leading roles in the Western Legends of the Fall and the bloodsucking blockbuster Interview with a Vampire, both in 1994, prompting People magazine to crown him the "Sexiest Man Alive" the next year. Fearing the label would limit his career, Pitt took on intense, often offbeat roles that proved he was more than just a pretty boy, such as a mentally unstable animal rights activist in 12 Monkeys (which earned him an Oscar nod) and the leader of an underground society in Fight Club. Pitt was again voted People's "sexiest man alive" in 2000. Finally ready to embrace his hunk status, Pitt played a suave, suit-clad criminal in Ocean's Eleven and a stunning shirtless warrior in Troy. He was more often in the spotlight thanks to his high-profile romances, including broken engagements to actresses Juliette Lewis and Gwyneth Paltrow, and a seemingly perfect marriage to Jennifer Aniston that ended in 2005. She filed for divorce after rumors circulated that he had taken up with his Mr. & Mrs. Smith costar Angelina Jolie. In 2006, after months of tabloid coverage of "Brangelina" flying around the globe fighting for human rights and adopting children, the couple revealed that Jolie was pregnant with Pitt's child.