The Victoria's Secret beauty will feature on an upcoming episode, in which she'll play one of three models who receive an anoymous threatening letter during a shoot for the sexy underwear brand.
Hawaii Five-0 executive producer Peter Lenkov tells Eonline.com, "We're all very excited to welcome our latest guest star, the head-turning, jaw-dropping, Behati Prinsloo, Victoria's Secret supermodel extraordinaire. Hawaii just got way hotter."
Prinsloo's acting debut will air in America on 3 December (12), the night before the annual Victoria's Secret Fashion Show is broadcast.
Maroon 5 frontman Levine recently joined the cast of another TV drama, American Horror Story.