The charitable stars have offered up the sum to the United Nations Refugee Agency to help displaced citizens in Pakistan.
Jolie, who is an ambassador for the UN, recently made a video to promote World Refugee Day, on June 20.
And she is due to meet Secretary of State Hillary Clinton in Washington, D.C., on Thursday to discuss the global refugee crisis.
The Hollywood couple also donated $1 million to St. John's hospital in Pitt's native Springfield, Missouri, to fund a new pediatric unit.
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