The 30-year-old Latina, who claims she was the "ugly duckling" of her family growing up, was honored for her sexy performance as Gabrielle Solis in the hit show.
Aniston, who played Friends' Rachel Green for ten years, came second in the survey by British supermarket Sainsbury's, followed by Sex and the City's Kim Cattrall as man-eating Samantha Jones in third place.
The Top Five Sexiest Female TV Stars of All-Time are:
1. Eva Longoria--Desperate Housewives
2. Jennifer Aniston--Friends
3. Kim Cattrall--Sex and the City
4. Pamela Anderson--Baywatch
5. Sarah Michelle Gellar--Buffy The Vampire Slayer
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